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== Atomic Structure and Periodicity == === Electron Configuration === The arrangement of elements in the periodic table directly reflects their electron configurations. Electrons occupy atomic orbitals according to the Aufbau principle, following the sequence: 1s β 2s β 2p β 3s β 3p β 4s β 3d β 4p β 5s β 4d β 5p β 6s β 4f β 5d β 6p β 7s β 5f β 6d β 7p Each element's position in the table corresponds to its outermost electron configuration, which largely determines its chemical behavior. {| class="wikitable" style="float:right; margin:0.5em; text-align:center;" ! style="text-align:right;" |β = ! 0 ! 1 ! 2 ! 3 ! 4 ! 5 ! 6 ! rowspan=2 | Shell capacity (2''n''<sup>2</sup>)<ref>{{cite web |date=6 May 2020 |title=Electron Configurations |url=https://www.chem.fsu.edu/chemlab/chm1045/e_config.html |access-date=17 April 2022 |website=www.chem.fsu.edu |publisher=Florida State University |archive-date=6 May 2022 |archive-url=https://web.archive.org/web/20220506074340/https://www.chem.fsu.edu/chemlab/chm1045/e_config.html |url-status=live }}</ref> |- ! style="text-align:right;" | Orbital ! s ! p ! d ! f ! g ! h ! i |- ! ''n'' = 1 | bgcolor="{{element color|s-block}}" | 1s | colspan=6 | | 2 |- ! ''n'' = 2 | bgcolor="{{element color|s-block}}" | 2s | bgcolor="{{element color|p-block}}" | 2p | colspan=5 | | 8 |- ! ''n'' = 3 | bgcolor="{{element color|s-block}}" | 3s | bgcolor="{{element color|p-block}}" | 3p | bgcolor="{{element color|d-block}}" | 3d | colspan=4 | | 18 |- ! ''n'' = 4 | bgcolor="{{element color|s-block}}" | 4s | bgcolor="{{element color|p-block}}" | 4p | bgcolor="{{element color|d-block}}" | 4d | bgcolor="{{element color|f-block}}" | 4f | colspan=3 | | 32 |- ! ''n'' = 5 | bgcolor="{{element color|s-block}}" | 5s | bgcolor="{{element color|p-block}}" | 5p | bgcolor="{{element color|d-block}}" | 5d | bgcolor="{{element color|f-block}}" | 5f | bgcolor="{{element color|g-block}}" | 5g | colspan=2 | | 50 |- ! ''n'' = 6 | bgcolor="{{element color|s-block}}" | 6s | bgcolor="{{element color|p-block}}" | 6p | bgcolor="{{element color|d-block}}" | 6d | bgcolor="{{element color|f-block}}" | 6f | bgcolor="{{element color|g-block}}" | 6g | bgcolor="{{element color|h-block}}" | 6h | | 72 |- ! ''n'' = 7 | bgcolor="{{element color|s-block}}" | 7s | bgcolor="{{element color|p-block}}" | 7p | bgcolor="{{element color|d-block}}" | 7d | bgcolor="{{element color|f-block}}" | 7f | bgcolor="{{element color|g-block}}" | 7g | bgcolor="{{element color|h-block}}" | 7h | bgcolor="{{element color|i-block}}" | 7i | 98 |- ! Subshell capacity (4β+2) | 2 | 6 | 10 | 14 | 18 | 22 | 26 | |} === Periodic Trends === Several key properties show regular patterns across the periodic table: # '''Atomic Radius''' #* Generally decreases from left to right across a period #* Increases down a group #* Shows pronounced first-row anomalies due to the absence of inner electrons # '''Ionization Energy''' #* Generally increases from left to right across a period #* Decreases down a group #* Reflects the difficulty of removing electrons # '''Electron Affinity''' #* Generally increases from left to right (excluding noble gases) #* Shows more complex patterns down groups #* Indicates tendency to accept electrons # '''Electronegativity''' #* Increases from left to right #* Decreases down groups #* Highest in fluorine, lowest in francium (excluding noble gases)
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